The group IV metal Zirconium (Zr) is an important material in the nuclear, aviation and biomedical industries due to its low neutron cross section, high-resistance to corrosion and low toxicity. Understanding the structural behavior of Zr at extreme pressures (P) and temperatures (T) has therefore been the subject of considerable theoretical and experimental effort. Dynamic compression, where the material is rapidly compressed over nanoseconds to microseconds, is a method which allows materials to be studied at P-T conditions beyond the reach of conventional static compression techniques. While Zr has already been the subject of numerous shock compression studies, the characterization of its structural behavior at high P-T conditions has been limited by a lack of lattice level information provided in these experiments. Our understanding of the phase transition kinetics associated with the alpha → omega phase transition has also suffered from the lack of in situ structural information. We used high-quality velocimetry and in situ X-ray diffraction from both an X-ray Free Electron Laser and a 3^rdgeneration synchrotron light source, to study the structural and melting behavior of Zr up to 200 GPa. Upon pressure release from the high pressure ω phase, our measurements provide an in situ, atomistic view of the ω → α transformation and its kinetics for the first time.


This work was performed under the auspices of the US Department of Energy by Lawrence Livermore National Laboratory under Contract No. DE-AC52-07NA27344